After an oil portrait by an unknown artist at Lambeth Palace. It is listed in inventories there and reproduced in engravings such as that published by W. Herbert on 15 February 1806 as a portrait of Katherine Parr. However, this identification has now been questioned, and the features of the sitter in this enamel, which do not resemble those in a newly authenticated likeness of King Henry VIII's sixth queen in the National Portrait Gallery, London (no. 4451), appear closer to those of Catherine of Aragon as depicted in miniatures by Lucas Hornebolte.

Signed, dated and inscribed on the counter-enamel in red paint: Katharine Parr / London Febr 1844 / Painted by Henry Pier. / Bone Enamel Painter / to Her Majesty & H.R.H. / Prince Albert &c. From / the Original in / Lambeth Palace.